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Physics · Lesson

Distinguish a temperature change from a phase change

When the heater is still on but the thermometer stops moving, it is natural to think something has gone wrong.

On this page
  1. What is happening at each stage of a heating curve?
  2. Worked example
  3. The mistake to watch for
  4. Check yourself
  5. Where this leads next

A substance being heated either changes temperature or changes state, and on a heating curve the two look completely different. A sloping section means the temperature is changing; a flat section means a change of state is happening. Questions ask you to identify each section, explain it in terms of particles and use the correct equation for the stage you are in.

This lesson follows interpreting an energy-temperature slope and sets up calculating latent energy.

What is happening at each stage of a heating curve?

During a sloping section, energy supplied increases the kinetic energy of the particles. They vibrate or move faster, so the temperature rises. The equation Q = m × c × Δθ applies here.

During a flat section, the energy supplied increases the potential energy of the particles as they are pulled apart or freed from their neighbours. The average kinetic energy stays the same, so the temperature is constant. Q = m × c × Δθ gives zero here, which is a clue that it is the wrong equation for this stage.

  1. Look at the graph shape and label each section as sloping or flat.
  2. Name the stage: solid warming, melting, liquid warming, boiling or gas warming.
  3. Choose the equation by stage: m × c × Δθ for sloping sections, the latent energy equation for flat sections.
  4. Use the time as a measure of energy if the power is steady: energy = power × time.

Worked example

A solid is heated by a steady 300 W heater. (Invented example data.) The temperature is recorded every minute:

Time (min)012345678
Temperature (°C)304560606060708090

Describe each stage and find the energy supplied during the flat section.

Step 1, stages: 0 to 2 min, the solid warms from 30 °C to 60 °C. From 2 to 5 min the temperature stays at 60 °C, so the substance is melting at 60 °C. From 5 to 8 min the liquid warms from 60 °C to 90 °C.

Step 2, compare the slopes: the solid rises 15 °C per minute and the liquid only 10 °C per minute. The same energy arrives each minute, so the liquid needs more energy per degree. Its m × c is larger.

Step 3, energy in the flat section: duration = 3 min = 180 s. E = P × t = 300 × 180 = 54 000 J.

Step 4, check: 300 W is 300 × 60 = 18 000 J per minute. Three minutes gives 3 × 18 000 = 54 000 J, which matches.

The mistake to watch for

A common slip is to say that nothing is happening during the flat section.

Mistaken answer: “The temperature is constant, so no energy is being transferred to the substance.”

The heater is still on, and 54 000 J is supplied in this example.

The correction is to say where the energy goes: it increases the potential energy of the particles while the substance changes state, so the temperature stays constant. The energy is transferred, but it is not used to raise the temperature.

Check yourself

1. In the example, what is the energy supplied in the first two minutes?

Show answer

2 min = 120 s. E = 300 × 120 = 36 000 J. Check: 2 × 18 000 J = 36 000 J.

2. During which time intervals is the average kinetic energy of the particles increasing?

Show answer

0 to 2 min and 5 to 8 min. The temperature is rising only in those intervals. In the flat section the average kinetic energy is constant.

3. Explain in one or two sentences why the temperature stays constant while the substance melts.

Show answer

The energy supplied is used to overcome the forces holding the particles in place, increasing their potential energy. The average kinetic energy does not change, so the temperature stays constant until melting is complete.

Where this leads next

The flat section can be calculated: continue with calculating latent energy, if your syllabus includes it. The heat calculations practice set includes heating-curve questions.

A flat line is easy to spot but harder to explain in words that earn marks. A teacher in online one-to-one Physics tuition can read your explanation and tighten each sentence.

Questions people ask

Why does temperature stay constant while a substance melts?

The energy supplied goes into weakening the forces between particles, increasing their potential energy, rather than making them move faster. Temperature relates to the average kinetic energy of the particles, so it does not change until the change of state is complete.

Is the heater still transferring energy during the flat section?

Yes. Energy is still transferred at the same rate if the power is steady. The flat section shows that the energy is not raising the temperature, not that the energy has stopped.

Do boiling and melting both show a flat section?

Yes, for a pure substance heated steadily. The first flat section is melting and the second, at a higher temperature, is boiling. The boiling section is usually longer for the same power because more energy is needed per kilogram.

Updated:

Your next step

If heating curves make sense in words but the explanation falls apart when you write it, a one-to-one teacher can listen to your reasoning and sharpen each sentence until it earns the marks.

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